
Hi Kate
Please do not remove the radiator cap if you've just used the car as this can be very dangerous and you could end up burning yourself as the steam vents out.
It could be a number of things and really the best way is to allow a garage to look at it and to see what they find and quote. You can then decide how to play it from there. Sometimes little problems when left create a larger one so it might be better to be safe than sorry.
I had similar happen to a BMW and it turned out to be a leak in the head gasket (3 year old!!!) which leaked water into number one cylinder and a side gasket popped as well due to the build up of pressure. Thankfully covered by warranty :)
I would also think if you had a leak the engine temperature gauge would be showing a hotter temp than normal and you would notice a drop in your fluid level. Check your owners handbook which will show you your engine bay and all the check points for oil, water and so on. Remember to check your dash warning lights to see if they show a fault as well as most have warning lights of some kind (slim chance but worth looking).
I just feel the safest way is for a mechanic to have a peep.
Regards
Stu