
You may have missed the early days, she may be an early ovulater, or she may have been mated a bit early, only time will tell, but generally bitches will not stand before the LH surge (two days before ovulation) more often not until ovulation, and in fact can't conceive until about two days after that.
Most experienced males will not waste their time on a bitch that isn't ready, and a virile males sperm can live for a week or more, and stay in good condition for at least 4 days. this is why bitches conception rate is around 90% as there is a good amount of wiggle room.