> the jr bitch keeps on humping the male puppy more violently and gets very angry with him about 20 times a day
When you say 'angry', could this be play? I'd imagine a JRT's idea of play is very vocal & rough? Also OTT play can seem very 'angry'. That would fit in with the humping.
When I first brought my (male) pup home and my (male) adult dog finally acepted him enough to play with, the play would sometimes get too OTT and result in the adult, over-excited and humping the pup like a loony.
I would just try to distract them from each other when a play session looked like it was getting too silly.