Yes, she can! If this is not a planned mating, call the vet first thing tomorrow to find out when you should take her in for the "morning-after" injections.
The average bitch ovulates day 10 to 12, and the egs become feritlizable about 2 days after, staying this way for about another two days.
the sperm of a fit dog can live in the bitches tract around a week, therefore it is very likely your bitch would become pregnant unless you take remedial action as suggested.