Has anyone ever used any kind of spray or tablet on a bitch in season that discourages intense interest from entire males?!

I am sure I already know the answer is no, but it is worth a shot. My husband's border collie bitch is currently in season and every six months we go through the angst of his male collies and my entire male GSD going off their food, trying to gain access to her through any means necessary, going off work and food etc. The worst culprit is my entire WL GSD male. He scales a six foot fence, opens doors, barks, howls and generally makes life difficult for himself and me! The rest of the time a nicer, more well adjusted and balanced GSD you could not find, but he turns into a real pain in the ass when she comes into season.