
If she got a mating yes, but I would always prefer at least two mattings over three days (or three one every day). so want another tomorrow.
Also if bitch or the dog aren't keen you know you were right and she is going over.
If she is happy to be mated it will catch any stray eggs, and possibly the semen will be better as the first mating will have cleared the tubes. If a dog hasn't been used for a while the first ejaculate will have more detritus.