
A few thoughts on the possible causes of seizures, some of which could be identified by tests:
It could be due to metabolic causes:
-Hypoglycemia or low blood sugar, has been suggested on this thread. This is quite common in Toy breed puppies.
-High blood ammonia levels also can lead to seizures. This metabolic disturbance is seen in dogs with liver disease (for example, portosystemic shunts in puppies).
-High levels of circulating uremic toxins due to kidney failure have been known to cause seizures.
There are also toxic substances which have accidentally been eaten which could cause fits - such as insecticides, old paint, tar, I'm sure there's more.
Fits can be due to encephalitis, or inflammation of the central nervous system. I'm not a Pug expert but I think there's a possibility that Pugs are susceptible to something like this.
So there are various reasons to conduct tests. You may never get a definitive answer as to cause, but at least you can rule things out.
And you don't have to have expensive MRI scans to see a neurologist. You can just have a consultation for much less money if you want. (Although I know you said you've got insurance.) Sometimes a neurologist's advice regarding medication can be useful.
And of course it could simply prove to be a one-off, let's hope so. If she was my dog, I would keep the appointment at your vet's and take it from there.